Q2.Given N2(g)+ 3H2(g)→ 2NH3(g);ΔrH0= –-92.4 kJ mol−1 What is the standard enthalpy of formation of NH3gas?
Answer : Option BExplaination / Solution: Standard Enthalpy of formation of NH3 is the energy change that take place when 1 mole of NH3 is formed from elements in standard state. For 2 moles of ammonia formation energy= –-92.4 kJ mol−1. For 1 mole energy =0.5 x–-92.4 kJ mol−1= -46.2 kJ mol−1
Answer : Option CExplaination / Solution: The number of electrons in Nitrogen are 7 and in oxygen are 8. Hence the number of electrons that would be present in the molecular orbitals in NO are 7 + 8 = 15. As the number of electrons are odd, all the electrons in NO molecule cannot be paired. Hence, a single electron would be present in a π*2p orbital. Therefore NO is an odd electron species and the gas is hence paramagnetic due to the presence of unpaired electron.
Q7.Aniline is separated from aniline-water mixture using following technique:
Answer : Option BExplaination / Solution:
Steam distillation is a special type of distillation(separation process) for temperature sensitive materials like natural aromatic compounds.It was a popular laboratory method for purification of organic compounds..
In the catalyzed decomposition of benzene diazonium chloride, Half life period is found to be independent of the initial concentration of the reactant. After 10 min, the volume of N2gas collected is 10 L and after the reaction is complete, it is 50 L. Hence, the rate constant of the reaction(in min –1) is