The number of chain isomers of are
n-pentane CH3CH2CH2CH2CH3
2-Methylbutane CH3CH(CH3)CH2CH3
2,2-Dimethylpropane CH3CH(CH3)2CH3
Wurtz reaction is used for the preparation of alkanes from alkyl halides in the presence of sodium and dry ether.For example: CH3Br + 2Na +BrCH3 ---------> CH3CH3 + 2NaBr
Thus two atoms of Na are used.