
White fumes appears because of formation of HCl on reaction with atmospheric moisture.
White fumes appears due to the formation of HCl gas. Anhydrous aluminium chloride is partly hydrolyzed by the moisture in the atmosphere and produces HCl gas. This HCl further combines with the moisture of the air and appears white fumes.
AlCl3 +3H2O --> Al(OH)3 +3HCl