Match the following
A) Pure nitrogen i) Chlorine
B) Haber process ii) Sulphuric acid
C) Contact process iii) Ammonia
D) Deacons Process iv) sodium azide (or) Barium azide

V2+ ( t2g3, eg0 ; CFSE =
3 x (-0.4)Δ0 = -1.2 Δ0)
Ti2+ ( t2g2, eg0 ; CFSE =
2 x (-0.4)Δ0 = -0.8 Δ0)
Statements given in
option (a) ,(b), and (c) are wrong.
The current statements
are
(a) since, the crystal
field stabilization is more in octahedral field , octahedral complexes are more
stable than square planar complexes.
(b) 

ρ = n × M / a3NA
for bcc
n = 2
M=39
nearest distance 2r =
4.52
