KOH →
K+ + OH-
10-5m 10-5m 10-5m
KOH (10-5m) → K+
(10-5m) + OH- (10-5m)
[OH-] = 10-5M.
pH= 14 - pOH
pH = 14 - ( - log [OH-]
)
= 14 + log [OH- ]
= 14 + log10−5
= 14−5
= 9.
17. The equivalent conductance of M/36 solution of a weak monobasic acid
is 6 mho cm2 equivalent –1 and at infinite dilution is
400 mho cm2 equivalent –1. The dissociation constant of
this acid is
α = Λ / Λo = 6/400
Ka =α2C
= 6/400 × 6/400 × 1/36
= 6.25 ×10−6
The reactions


(a) Zn2+ (d10
⟹
diamagnetic)
(b) Co3+ (d6
Low spin ⟹ t2g6, eg0
diamagnetic)
(c) Ni2+ (d8
Low spin ⟹ t2g6, eg2
paramagnetic)
(d) [Ni(CN)4]2-
(dsp2 ; square planar, diamagnetic)