
(a) Fe2+
(b) Fe3+
(c) Fe0

Assertion: rate of reaction doubles
when the concentration of the reactant is doubles if it is a first order
reaction.
For a first reaction, If
the concentration of reactant is doubled, then the rate of reaction also
doubled.
Rate constant is
independent of concentration and is a constant at a constant temperature,
K a =1 ×10-3
pH=4
[salt] /
[Acid] = ?
pH = pKa +log {[Salt]/[Acid]}
4 = - log10 (1 ×10-3 ) + log {[Salt]/ [Acid]}
4 = 3 + log ([Salt]/ [Acid])
1= log10 ([Salt]/[Acid])
[Salt] / [Acid] =101
i.e., [Salt] / [Acid] = 1 / 10
1:10