

let
the number of Fe2+ ions
in the crystal be x
the number of Fe3+ ions
in the crystal be y
total number of Fe2+ and
Fe3+ ions is
x + y
given that x + y = 0.93
the total charge =0
x (2+) + (0.93 –x) (+ 3) −2 = 0
2x + 2.97 −3x −2 = 0
x = 0.79
Percentage of Fe3+
= [ ( 0.93 −0.79) / (0.93) ] 100 = 15.05%

(x+y) kJmol-1
(x+y) 103 Jmol-1
C5H5N + H-OH ↔ C5H5 NH + OH-
(α2C) / (1-α ) =Kb
α2C =∼ Kb
α = √ [ Kb
/ C ] = √[ 1.7 ×10-9 / 0.1 ]
= √1.7 × 10-4
= √1.7 × 10−4 × 100
Percentage of dissociation = 1.3 ×10-2 = 0.013 %
Q =It
= 1A×60S
96500 C charge ≡ 6.022 ×1023
electrons
60 C charge ≡ [ 6.022 ×1023
/ 96500
] × 60
= 3.744 ×1020 electrons