-I effect increases the acidity. If electronegativity is high, -I effect is also high.
The electronic
configuration t2g3, eg2
[3x(-0.4) + 2(0.6)]Δ0
[-1.2 + 1.2]Δ0 =0
in diamond carbon forming fcc.
Carbon occupies corners and face centres and also occupying half of the
tetrahedral voids.
(Nc/8) + (Nf/2)
+ 4 C atomos in Td voids
(8/8) + (6/2) + 4 = 8
BF3 → elctron deficient → Lewis
acid
PF3 → electron rich → lewis
base
CO → having
lone pair of electron → lewis base
F- → unshared pair of electron → lewis base
m=ZIt
(41min 40sec = 2500 seconds)
Z = m/ (n × 96500) = 40 / (2 ×
96500)
m = Zit
= ( 40 × 3.86 × 2500 ) / (2 × 96500)
= 2g