Correct
Statement: Critical temperature
of CO2 is 304 K. It means that CO2 cannot be liquefied
above 304 K, whatever the pressure may applied.
Pressure is inversely proportional to volume
A + B ⇌ C
KC= [C] / [A] [B]
if [A] and [B] are doubled, [C] increases 4 times to
maintain KC as constant.
∴
equilibrium constant will remain the same – option (d)
During compression, energy of the system increases,
in isothermal condition, to main-tain temperature constant, heat is liberated
from the system. Hence q is negative.
During compression entropy decreases.
During compression work is done on the system,
hence w is positive
π = CRT
π = [ W/MV ] . RT
M = WRT / π V
= [1.26 x 0.083x300] / [2.52x10-3x0.2]
= 62.22 Kg mol-1

