
mass of deuterium = 2 × mass of protium
If all the 1.2 g hydrogen is replaced with
deuterium, the weight will become 2.4g. Hence the increase in body weight is
(2.4 – 1.2 = 1.2 g)

Rate of diffusion α 1/√m
mNH3 = 17 ; mHCl = 36.5
γNH3 > γHCl
Hence white fumes first formed near hydrogen
chloride
In the equilibrium,
2A(g) ⇌ 2B(g) + C2(g)
the equilibrium concentrations of A, B and C2 at
400 K are 1 × 10–4 M, 2.0 × 10–3 M, 1.5 × 10–4
M respectively. The value of Kc for the equilibrium at 400 K is
[A] = 1 × 10–4
M ;
[B] = 2 × 10–3 M
[C] = 1.5 × 10–4 M
2A (g) ⇌ 2B(g) + C2(g)

Ptotal = P1 + P2
= P1x1 + P2x2 (x1 + x2 = 1)
= P1 (1 – x2) + P2x2
(x1 = 1 – x2)
= P1 – P1x2 + P2x2
= P1 – x2 (P1 – P2)