For the reduction of silver ions with copper metal the standard cell potential was found to be +0.46V at 25°C. The value of standard Gibbs energy, ΔG° wll be (F = 96500 C mol−1)
Answer : Option CExplaination / Solution:
In cases of halogen derivatives of phenols or aniline or benzoic acid etc, it is very helpful to understand that all halogens when attached to benzene ring exerts -I as well as +R effect.
In case of Cl, Br and I, the +R effect has almost no effect on reactivity, acidic character or basic character of benzene ring. It is due to very less effective overlapping involving 2p of carbon and 3p or 4p or 5p of halogen.
Hence, only -I effect becomes the deciding factor, which is most dominant from ortho-position and least effective from para-position. So m chlorophenol is most acidic.
Q10.Anisole reacts with a mixture of concentrated sulphuric and nitric acids to yield a mixture of ortho and para nitroanisole
Answer : Option CExplaination / Solution:
Para isomer is major because ethere is no steric hinderance and also at para +M effect will work effectively.
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